Migrate pydantic validators to field_validators

In `src/app/schemas/rate_limit.py`:

```
PydanticDeprecatedSince20: Pydantic V1 style `@validator` validators are deprecated. You should migrate to Pydantic V2 style `@field_validator` validators, see the migration guide for more details. Deprecated in Pydantic V2.0 to be removed in V3.0. See Pydantic V2 Migration Guide at https://errors.pydantic.dev/2.4/migration/
```