You can customize the appointment time format by using the TimeFormat property of AgendaViewStyle in Xamarin.Forms SfSchedule.
XAML
You can set “HH: mm” to TimeFormat property of AgnedaViewStyle to show appointments with 24 hr time format.
<schedule:SfSchedule.MonthViewSettings>
<schedule:MonthViewSettings ShowAgendaView="True">
<schedule:MonthViewSettings.AgendaViewStyle>
<schedule:AgendaViewStyle TimeFormat="HH:mm"/>
</schedule:MonthViewSettings.AgendaViewStyle>
</schedule:MonthViewSettings>
</schedule:SfSchedule.MonthViewSettings>
Note: Agenda View Appearance customization is not applicable for UWP and WPF platforms.
KB article - How to customize the appointment time format in Xamarin.Forms Schedule (SfSchedule)